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However, there is scarce information about the quinolinyl derivatives of adamantaneamines, as only two publications (5,6) deal with 4-quinolinyl derivatives which demonstrated anti-malarial activity, and one describes the synthesis of 2-quinolinyl-substituted adamantane-1,3-diamine. All these compounds were obtained using non-catalytic methods.
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For the synthesis of 1-(9-amino-1,7-dicarba-closo-dodecaboran-1-yl)-6-hydroxybenzothiazole, iodination was performed before introducing the benzothiazole group, and the amino group was subsequently introduced in six steps. Both compounds were radiolabelled with carbon-11 using (11C)CH3OTf as the labelling agent. Radiolabelling yields and.
ChemInform Abstract: 1,2-Functionalized Imidazoles as Palladium Ligands: An Efficient and Robust Catalytic System for the Fluorine-Free Hiyama Reaction.
A highly efficient direct arylation process of benzylic amines with arylboronates was developed that employs Ru catalysis. The arylation takes place with greatest efficiency at the benzylic sp3 carbon. If the distance to the activating aryl ring is increased, arylation is still possible but the yield drops significantly. Efficiency of the CH activation was found to be significantly increased.
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Improved Catalysts and Ligands for Asymmetric Synthesis - Aldrichimica Acta Vol. 41 No. 1 - Free download as PDF File (.pdf) or read online for free. Practical Organocatalysis with (S)- and (R)-5-Pyrrolidin-2-yl-1H-tetrazoles Aminophosphine Catalysts in Modern Asymmetric Synthesis.
